durban widely used antioxidant 6ppd rubber additives
durban widely used antioxidant 6ppd rubber additives
durban widely used antioxidant 6ppd rubber additives
durban widely used antioxidant 6ppd rubber additives
durban widely used antioxidant 6ppd rubber additives
  • Are p phenylenediamine (PPD) antioxidants in recycled tire rubber products toxic?
  • Recently, roadway releases of N, N ′-substituted p -phenylenediamine (PPD) antioxidants and their transformation products (TPs) received significant attention due to the highly toxic 6PPD-quinone. However, the occurrence of PPDs and TPs in recycled tire rubber products remains uncharacterized.
  • Which industrial rubber additives have higher chemical concentrations?
  • Furthermore, we quantified 15 other industrial rubber additives (including bonding agents, vulcanization accelerators, benzotriazole and benzothiazole derivatives, and diphenylamine antioxidants), observing that PPD-derived chemical concentrations were 0.5–6 times higher than these often-studied additives.
  • Do recycled tire rubber products contain PPDS and TPS?
  • However, the occurrence of PPDs and TPs in recycled tire rubber products remains uncharacterized. Here, we analyzed tire wear particles (TWPs), recycled rubber doormats, and turf-field crumb rubbers for seven PPD antioxidants, five PPD-quinones (PPDQs), and five other 6PPD TPs using liquid chromatography-tandem mass spectrometry.
  • Are rubber antioxidants a rational design?
  • The development of medical antioxidants also inspires the rational design of rubber antioxidants. Recently, Sun, et al. synthesized a novel antioxidant (APPT) containing aromatic amine, thiourea and allyl groups by the reaction between N-phenyl-p-phenylenediamine and allyl isothiocyanate (Fig. 3 b) .

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